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Journal of APPLIED BIOMEDICINE
ISSN 1214-0287 (on-line)
ISSN 1214-021X (printed)

Volume 5 (2007), No 3, p 167-170



Kinetics of decompositition of organophosphate Fenitrothion by decontaminating foam-making blends

Jiri Cabal, Kamil Kuca, Jitka Micova

Address: Department of Toxikology, Faculty of Military Health Sciences, University of Defence, Trebesska 1575, 500 01 Hradec Kralove, Czech Republic
cabal@pmfhk.cz

Received 17th April 2007.
Revised 14th May 2007.
Published online 30th July 2007.

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SUMMARY
The hydrolytic efficacy of foam-making blends on the basis of cationic and nonionic surfactants and hydrogen peroxide was tested against the organophosphate Fenitrothion. The length of alkyl chains in both classes of surfactants and their mutual ratios are not parameters which significantly influenced the reactivity of blends. On the other hand, an increase in the hydrogen peroxide concentration induced a significant increase in the velocity of hydrolysis of Fenitrothion.

KEY WORDS
foams; decontamination; organophosphate; cationic surfactants


REFERENCES
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Cabal J, Kassa J, Severa J: A comparison of the decontamination efficacy of foam-making blends based on cationic and nonionic tensides against organophosphorus compounds determined in vitro and in vivo. Hum Exp Toxicol 22:507-514, 2003.

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CITED

Chen C-C, Huang M-J, Lin Y-T, Ko F-H, Chang E-Y. Microfluid on chip transesterification reaction and real-time monitor by PN diode photodetector. Int J Electrochem Sci. 7: 12621-12632, 2012.

Marek J, Buchta V, Soukup O, Stodulka P, Cabal J, Ghosh KK, Musilek K, Kuca K. Preparation of quinolinium salts differing in the length of the alkyl side chain. Molecules. 17: 6386-6394, 2012.

Cabal J, Micova J, Kuca K. Kinetics of hydrolysis of organophosphate soman by cationic surfactant Resamin AE. J Appl Biomed. 8: 111-116, 2010.

Tiwari S, Ghosh KK, Marek J, Kuca K. Cationic Micellar-catalyzed hydrolysis of pesticide fenitrothion using alpha-nucleophiles. Lett Drug Des Discovery. 7: 194-199, 2010.

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