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<PublisherName>University of South Bohemia, Ceske Budejovice and Versita, Warsaw</PublisherName>
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<Journal>
<JournalInfo JournalType="Journals">
<JournalPrintISSN>1214-021X</JournalPrintISSN>
<JournalElectronicISSN>1214-0287</JournalElectronicISSN>
<JournalTitle>Journal of Applied Biomedicine</JournalTitle>
<JournalCode>JAB</JournalCode>
<JournalID>121649</JournalID>
<JournalURL>http://versita.metapress.com/link.asp?target=journal&id=121649</JournalURL>
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<Volume>
<VolumeInfo>
<VolumeNumber>8</VolumeNumber>
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<Issue>
<IssueInfo IssueType="Regular">
<IssueNumberBegin>2</IssueNumberBegin>
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<IssueSequence>000008000220100601</IssueSequence>
<IssuePublicationDate>
<CoverDate Year="2010" Month="6" Day="1"/>
<CoverDisplay>Number 2 / June 2010</CoverDisplay>
</IssuePublicationDate>
<IssueID>LR323T458627</IssueID>
<IssueURL>http://versita.metapress.com/link.asp?target=issue&id=LR323T458627</IssueURL>
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<Article ArticleType="Original">
<ArticleInfo Free="No" ESM="No">
<ArticleDOI>10.2478/v10136-009-0009-5</ArticleDOI>
<ArticlePII>63H14R88T6L34657</ArticlePII>
<ArticleSequenceNumber>8</ArticleSequenceNumber>
<ArticleTitle Language="En">Kinetics of hydrolysis of organophosphate soman by cationic surfactant Resamin AE</ArticleTitle>
<ArticleFirstPage>111</ArticleFirstPage>
<ArticleLastPage>116</ArticleLastPage>
<ArticleHistory>
<RegistrationDate>20100524</RegistrationDate>
<ReceivedDate>20100524</ReceivedDate>
<Accepted>20100524</Accepted>
<OnlineDate>20100524</OnlineDate>
</ArticleHistory>
<FullTextFileName>63H14R88T6L34657.pdf</FullTextFileName>
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<ArticleHeader>
<AuthorGroup>
<Author AffiliationID="A1">
<GivenName>Jiří</GivenName>
<Initials/>
<FamilyName>Cabal</FamilyName>
<Degrees/>
<Roles/>
</Author>
<Author AffiliationID="A1">
<GivenName>Jitka</GivenName>
<Initials/>
<FamilyName>Míčová</FamilyName>
<Degrees/>
<Roles/>
</Author>
<Author AffiliationID="A1 A2">
<GivenName>Kamil</GivenName>
<Initials/>
<FamilyName>Kuča</FamilyName>
<Degrees/>
<Roles/>
</Author>
<Affiliation AFFID="A1">
<OrgDivision/>
<OrgName>Department of Toxicology, Hradec Králové, Czech Republic</OrgName>
<OrgAddress/>
</Affiliation>
<Affiliation AFFID="A2">
<OrgDivision/>
<OrgName>Center of Advanced Studies, Faculty of Military Health Sciences, Hradec Králové, Czech Republic</OrgName>
<OrgAddress/>
</Affiliation>
</AuthorGroup>
<Abstract Language="En">This experiment tested the reactivity of the cationic surfactant Resamin AE [N-(2-hydroxyethyl)-N-(2-hydroxy-4-oxa(C14÷22-alkyl))-N, N-dimethylammonium chloride] with organophosphonate soman. It was confirmed that soman is incorporated in the micelle of Resamin AE and that the hydroxyl group or Resamin AE supports the hydrolysis of this organophosphonate. A further increase in reactivity was achieved by the addition of hydrogen peroxide into the reaction mixture. In contrast, if the concentration of neutral salts was increased, a decrease in the velocity of the hydrolysis was obtained. The hydrolytic efficacy of Resamin AE was also compared with that of hexadecyldimethyl-(2-hydroxyethyl)-ammonium bromide. Resamin AE appeared to be a more efficacious hydrolytic agent than other similar compounds due to its advantageous chemical structure.</Abstract>
<KeywordGroup Language="En">
<Keyword>cationic surfactants</Keyword>
</KeywordGroup>
<KeywordGroup Language="En">
<Keyword>micelar catalysis</Keyword>
</KeywordGroup>
<KeywordGroup Language="En">
<Keyword>soman</Keyword>
</KeywordGroup>
<KeywordGroup Language="En">
<Keyword>decontamination</Keyword>
</KeywordGroup>
<KeywordGroup Language="En">
<Keyword>Resamin AE</Keyword>
</KeywordGroup>
<biblist>
<bib-other>
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</bib-other>
<bib-other>
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</bib-other>
<bib-other>
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<bib-other>
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<bib-other>
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</bib-other>
<bib-other>
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<bib-other>
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